Electrocatalytic interconversion of NADH and NAD(+) by Escherichia coli flavohemoglobin.

نویسندگان

  • S Shipovskov
  • A Bonamore
  • A Boffi
  • E E Ferapontova
چکیده

E. coli flavohemoglobin, oriented at electrodes via amphiphilic polymyxin B, electrocatalytically interconverts NADH and NAD(+) at its heme potentials operating as an electron transfer relay between the electrode and the protein FAD, where NADH/NAD(+) is transformed. The results are crucial for the development of NAD(+)-dependent bioelectrodes for biosynthesis, biosensors and biofuel cells.

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عنوان ژورنال:
  • Chemical communications

دوره 51 89  شماره 

صفحات  -

تاریخ انتشار 2015